Biocatalysts Immobilized in Ultrathin Ordered Films

Biocatalysts Immobilized in Ultrathin Ordered Films

The immobilization of enzymes and other proteins into ordered thin materials has attracted considerable attention over the past few years. This research has demonstrated that biomolecules immobilized in different [Langmuir-Blodgett (LB)/Langmuir-Schaefer (LS)] matrixes retain their functional characteristics to a large extent. These new materials are of interest for applications as biosensors a...

Ultrathin, ordered oxide films on metal surfaces.

Metal oxides and oxide thin films are extensively used as active catalysts and catalytic supports, as well as in many other important technical applications. Unlike TiO(2), which is a semiconductor and can be investigated using a variety of surface science techniques, most metal oxides are insulators, which seriously restricts their use as model surfaces with modern surface science techniques. ...

Superparamagnetic ultrathin films

Surface Morphological Evolution of Ultrathin P4VP Films and Generation of Ordered Patterns on Graphite

The spin-coated thin-film morphology of poly(4-vinylpyridine) has been studied by AFM; the dark lines or disks (circular holes) in the AFM height images correspond to the depressed regions. An epitaxy-like ‘‘nano-trench’’ pattern was observed in the noncrystalline polymer film deposited on the crystalline graphite substrate. The transition from surface-templated to isotropic dewetting occurs du...

Wrinkling of Ultrathin Polymer Films

This paper presents a bilayer model to account for surface effects on the wrinkling of ultrathin polymer films. Assuming a surface layer of finite thickness, effects of surface properties on the critical strain, the equilibrium wavelength, and the wrinkle amplitude are discussed in comparison with conventional analysis. Experimental measurements of wrinkling in polymer films with thickness rang...